Abstract: The structural and electrochemical properties of gold nanoparticles biosynthesized from Rhus coriaria L. (Rc@AuNPs) were comprehensively investigated and characterized. R. co-riaria (sumac) served as a natural gold reducing and capping agent due to its rich poly-phenolic and phytochemical composition, enabling a sustainable, low-cost, and environ-mentally friendly synthesis of Rc@AuNPs. The electrochemical behavior of the hybrid material was evaluated using cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). Rc@AuNPs exhibited specific capacitances of 129.48 F/g, 156.32 F/g, and 280.37 F/g in H₂SO₄, Na₂SO₄, and KOH electro-lytes, respectively, indicating strong potential for supercapacitor and energy-storage ap-plications. GCD analysis further showed Csp values of 107.69 F/g (H₂SO₄), 133.23 F/g (Na₂SO₄), and 348.34 F/g (KOH), confirming the highest charge-storage performance in basic media. EIS measurements supported these results, yielding ESR values of 67.96 Ω in H₂SO₄, 64.42 Ω in Na₂SO₄, and a notably lower 24.43 Ω in KOH, consistent with its higher ionic conductivity and more efficient charge transfer. Overall, the superior Csp and low ESR observed in KOH demonstrate the excellent capacitive behavior of Rc@AuNPs. These biosynthesized gold nanoparticles represent a promising and sustainable electrode mate-rial for high-performance energy-storage technologies.

Abstract: The textile industries mostly rely on synthetic dyes, which contains nonbiodegradable components and high toxicity make its use environmentally hazardous. The present research delves into the unique application of proteins extracted Black Soldier Fly (BSF), as a natural dyes for wool fabrics. The hydrolyzed proteins extracted from each insect material (larvae, cocoons and flies) using superheated water at 170 °C for 1 h were used as natural dyes for dyeing wool fabrics with and without mordant (ferrous sulfate, 5% o.w.f.). Fabrics treated with mordant-free protein hydrolysate derived from cocoons showed best results with an increase in color strength (K/S value) from 0.43 to 2.78 with an increasing dye concentration from 2% to 50% o.w.f. . Color fastness to washing shows that dyed fabrics undergo variable color changes (from grade 4 to grade 1) but release little dye onto other fabrics, especially wool and synthetic fibers. Dry and wet rubbing color fastness tests showed overall variable color fastness, with little color loss on the abraded reference fabric. Overall, this work highlights the potential of protein hydrolysate from BSF as a natural and environmentally friendly dye, which may represent a promising alternative to synthetic dyes in the textile industry.

Abstract: Silica–chitosan hybrid composites containing up to 3.5 % chitosan were prepared via a reproducible and simple sol–gel route through the hydrolysis and condensation of tet-raethoxysilane (TEOS). The obtained gels were systematically characterized in terms of their textural, optical and thermal properties using UV–Vis spectroscopy, TG/DTA analysis, scanning electron microscopy (SEM), X-Ray diffraction and thermal conduc-tivity measurements. The bulk gel density was found to increase with chitosan content, indicating gradual compaction of the silica network and high sample homogeneity. These structural changes were accompanied by alterations in thermal stability, optical transparency, and heat transfer properties. DTA analysis revealed a broad exothermic feature, which may indicate a thermally induced process, such as partial carbonization. The resulting composites are suitable for various applications, including thermal insu-lation with controlled thermal conductivity, optical devices, biocompatible coatings, adsorbents for pollutant removal, controlled drug delivery, catalytic supports, and sensors. UV/Vis measurements display an intense absorption feature of the composites at 280 – 305 nm, which is promising for optical filter applications in combination with the increased mechanical stability due to chitosan addition.

Abstract: The paper focuses on materials characterization and «in vivo» biocompatibility tests of Ti6Al7Nb alloys microdoped by 0.3 wt. % of rareearth elements (REE) to use it as perspective materials to produce personalized medical implants. All Ti6Al7Nb0.3REE alloys (REE Y, Ce, La) were produced by electric arc melting method and characterized by scanning electron microscopy (SEM), optical microscopy (OM), energy-dispersive Xray spectroscopy analysis (EDX), helium pycnometer as well as reducing/oxidation melting methods. The measured true densities increased in the order: Ti−6Al−7Nb−0.3Y (4.4563 ± 0.1075 g/cm³) < Ti−6Al−7Nb−0.3Ce (4.7255 ± 0.2853 g/cm³) < Ti−6Al−7Nb−0.3La (4.8019 ± 0.0111 g/cm³). Diffraction analysis was performed to indicate phases composition and calculate crystallites sizes, crystal orientation and lattice parameters that confirmed REEmicrodoping due to increase of lattice volume. The single-phase Ti6Al7Nb0.3Y alloy had the finest αTi crystallites (22.32 nm), the larger αTi crystallites in the dualphase Ti6Al7Nb0.3Ce and Ti6Al7Nb0.3La (30.77 nm and 29.83 nm, respectively) suggest that the presence of the βTi phase. Hardness (H) and elastic modulus (E) were indicated by nanoindentation and increased in the order: Ti−6Al−7Nb−0.3La (4.01 GPa and 17.7 GPa respectively) < Ti−6Al−7Nb−0.3Y (4.39 GPa and 137 GPa respectively ) < Ti−6Al−7Nb−0.3Ce (4,67 GPa and 146 GPa respectively). In vivo tests showed that Ti6Al7Nb0.3La alloy had statistically significant increase of local inflammation at the one-week mark needed to further research and explanation as well, that could be indicator of toxicity in comparison with other studied alloys.

Abstract: The petroleum industry faces intensifying challenges related to the depletion of easily accessible reservoirs and the growing energy demand, necessitating the adoption of ad-vanced chemical agents that can operate under extreme conditions. Cationic gemini sur-factants, characterized by their unique dimeric architecture consisting of two hydrophilic head groups and two hydrophobic tails, have emerged as superior alternatives to con-ventional monomeric surfactants due to their enhanced interfacial activity and physico-chemical resilience. This review provides a comprehensive analysis of the literature concerning the molecular structure, synthesis, and functional applications of cationic gemini surfactants across the entire oil value chain, from extraction to refining. The analysis reveals that gemini surfactants exhibit critical micelle concentrations signifi-cantly lower than their monomeric analogues and maintain stability in high-temperature and high-salinity environments. They demonstrate exceptional efficacy in enhanced oil recovery through ultra-low interfacial tension reduction and wettability alteration, while simultaneously serving as effective drag reducers, wax inhibitors, and dual-action bio-cidal corrosion inhibitors in transportation pipelines. Cationic gemini surfactants repre-sent a transformative class of multifunctional materials for the oil industry.

Abstract: Expanding the chemical diversity of DNA-encoded libraries (DELs) is crucial for identifying binders to emerging drug targets using DEL technology. In the present study, as part of our ongoing efforts to develop on-DNA diazide platforms (D-DAPs)—platform molecules possessing both aromatic and aliphatic azide groups on a single core reactive scaffold—we have designed and synthesized a new compact diazide platform, designated as a compact D-DAP (C-D-DAP). This molecule is based on a low-molecular-weight reactive scaffold, 3-azido-5-(azidomethyl)benzoic acid, to facilitate small-molecule drug discovery targeting enzymes and G protein-coupled receptors (GPCRs). Furthermore, we established two distinct stepwise warhead construction strategies that exploit the chemoselective transformations of the azide groups in the C-D-DAP, which exhibit different reactivities. In addition, four virtual DELs were generated based on stepwise warhead elaboration from the C-D-DAP scaffold. Comparative chemical diversity analysis against bioactive compounds from ChEMBL revealed that these virtual libraries populate structural regions that are sparsely represented among known molecules. Each virtual library also occupies a distinct region of structural space relative to the others and displays intermediate quantitative estimate of drug-likeness (QED) values.

Abstract: Al–Zn–Ca alloys are good candidates for industrial electronics and electric vehicles due to their high thermal conductivity, castability, and corrosion resistance, but their strength requires improvement. This study investigates how Sc and Zr additions affect the microstructure, thermal, mechanical, and corrosion properties of an Al–3wt%Zn–3wt%Ca base alloy. Microstructural analysis showed that substituting Sc with Zr did not drastically alter the phase composition but changed the elemental distribution: Sc was uniform, while Zr segregated to dendritic cores. Zr addition also refined the grain size from 488 to 338 μm. An optimal aging treatment at 300 °C for 3 hours was established, which enhanced hardness for all alloys via precipitation of Al3Sc/Al3(Sc,Zr) particles. However, this Zr substitution reduced thermal conductivity (from 184.7 to 168.0 W/mK) and ultimate tensile strength (from 269 to 206 MPa), though it improved elongation at fracture (from 4.6 to 7.1%). All aged alloys exhibited high corrosion resistance in 5.7% NaCl + 0.3% H2O2 solution, with Zr-containing variants showing a lower corrosion rate and better pitting resistance. The study confirms the potential of tuning Sc/Zr ratios in Al–Zn–Ca alloys to achieve a favorable balance of strength, ductility, thermal conductivity, and corrosion resistance.

Abstract: Molten salts are increasingly regarded as promising fluids for high-temperature heat transfer, thermal energy storage, and advanced reaction processes, including concentrated solar power (CSP), molten salt oxidation (MSO), and next-generation nuclear reactors. Among these materials, the ternary eutectic mixture Li₂CO₃–Na₂CO₃–K₂CO₃ (32.12–33.36–34.52 wt%) has emerged as a leading candidate due to its wide operating temperature range and favourable thermodynamic characteristics. Despite its relevance, substantial inconsistencies and gaps remain in the available thermophysical property data, posing challenges for reliable design, modelling, and industrial deployment. This work revisits the Li₂CO₃–Na₂CO₃–K₂CO₃ eutectic through a critical assessment of the literature from its reported melting point at 397 °C (670 K) up to approximately 1200 K. Using a methodology inspired by IUPAC-supported strategies previously applied to common liquids such as water and hydrocarbons, we examine the quantity, quality, and coherence of existing measurements. Reference correlations are proposed only where the data are sufficiently robust to justify them. The analysis highlights a pressing need for more accurate and comprehensive measurements—particularly for heat capacity, thermal conductivity, and viscosity—to enable the development of reliable standard reference correlations. Addressing these data deficiencies is essential for advancing the safe and efficient use of molten carbonates in high-temperature energy technologies.

Abstract: Background: Recent studies have suggested significant antimicrobial properties of silver nanoparticles (AgNPs), offering a ray of hope during the height of antibiotic resistance. However, their efficacy largely depends on the particle size and colloidal stability. Although higher stability of AgNPs is associated with improved antimicrobial activity, excessive stability weakens their reactivity with the bacterial membrane. The objective of the research is to evaluate different reducing agent combinations to achieve optimal particle size and colloidal stability for maximum bactericidal efficacy. Materials and Methods: The synthesis of AgNPs was carried out using silver nitrate using five different chemical reduction methods to compare their antimicrobial activity. After purification, the freeze-dried AgNPs were characterized by UV-visible spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and dynamic light scattering (DLS). The minimum bactericidal concentration (MBC) of the AgNP formulations were investigated by plate counting method against the methicillin-resistant E. coli. Finally, the synthesized AgNPs were tested against the resistant strains of E. coli, Salmonella, Klebsiella, Bacillus, and Staphylococcus by the well diffusion method to evaluate and compare their inhibition zones. Results and Discussions: The average particle size for different formulations of nanoparticles ranges from 30.91 nm to 93.85 nm, while the zeta potential ranges from -8.0 mV to -41.1 mV. The minimum bactericidal concentration (MBC) for all AgNP formulations was determined against gram-negative E. coli, and AgNPs synthesized with only trisodium citrate were found to be the most effective with 99.75% bactericidal efficacy at 20 ppm concentration due to their optimal particle size and stability. However, AgNPs synthesized with polyethylene glycol and polyvinyl pyrrolidine were found to be the most effective against the resistant bacterial strains in the well diffusion assay. Conclusion: The reducing agents affect the particle size and stability of synthesized AgNPs, resulting in significant variations in their antibacterial activity, warranting further study.

Abstract: There is a growing demand for plant-derived antioxidants to replace synthetic ones in skincare applications. Phytochemicals are characterized by certain limitations, including poor bioavailability and chemical instability, which affect their industrial exploitation. Tomato peel extract has been used as a source of lycopene, which is renowned for its an-tioxidant properties. To improve the bioavailability of extracted lycopene, polymeric (Poly-lactic-co-glycolic acid) nano-carriers were synthesized by comparing two non-ionic surfactants, Polyvinyl alcohol and Tween 20. The impact of surfactants has been studied by evaluating: i) colloidal stability determined by Dynamic Light Scattering; ii) lycopene retention and bioactivity over time, as measured by spectrophotometric assays; iii) biolog-ical interactions on 2D and 3D culture keratinocytes and melanocytes cells. It was found that both surfactants enable the formation of stable lycopene-loaded nanoparticles sus-pensions; however, greater colloidal stability was exhibited by nanoparticles prepared with Tween 20. PVA, on the other hand, provided greater nanoparticles stability in terms of loaded lycopene retention and antioxidant activity. Tween 20 surfactant improves in-ternalization of lycopene-loaded nanoparticles in human skin spheroids. It was demon-strated that both surfactants provided excellent intracellular antioxidant activity of lyco-pene. This was observed in keratinocytes, melanocytes, adherent cells and spheroids, suggesting interesting skincare applications.

Abstract: A co-extrusion system, consisting of two sequential impregnation modules equipped with two heating systems, has been developed aimed at forming carbon yarns impregnated with thermoplastics. It has been shown that to ensure complete impregnation of the formed yarn, it is necessary to maintain the temperature in the extruders at 60-80 °C above the melting temperature of the polymer used. The highest strength achieved in the impregnated yarns was 3.3 GPa, which is 67% of the strength of raw carbon fiber. The degree of strength attained is determined primarily by the viscosity of the polymer melt; the minimum strength of 2.3 GPa and the greatest damage to the carbon fiber during impregnation was observed with the most viscous polymer. For all the studied samples, the elastic modulus is 210-220 GPa, which indicates good orientation and uniform drawing, allowing the rigidity of the raw carbon fiber to be almost completely realized.

Abstract: Synthetic Amorphous Silica (SAS) is produced and marketed since the early 1940’s and can be regarded as a nanostructured material since the first production even though the term ‘nano’ was not defined back then, and early publications describe the structure often as ‘milli-micron’. The present paper of Evonik Industries AG reviews the history of innovation and production of this “seasoned”, but evergreen product.

Abstract: The first hydrogenation behavior of the gas atomized Ti48.8Fe46.0Mn5.2 alloy was system-ically investigated. The as-received powder showed no hydrogen absorption due to the long air exposure before the hydrogenation tests. To overcome this, 5 passes of cold rolling were employed as an activation strategy. Cold rolling introduced cracks and defects that facilitated hydrogen diffusion, enabling the alloy to successfully absorb hydrogen. The influences of temperature, constant driving force, and hydrogen pressure on the first hydrogenation were evaluated. The results indicated that the first hydro-genation follows an Arrhenius behavior, with calculated activation energies of 69 and 57 kJ/mol H2. The observed difference in activation energies is likely associated with the variation of the driving force under constant pressure conditions. The pre-exponential factor (A) was found to be pressure-dependent, following the equation A = A₀ (P/P₀)1.8, where A₀ = 1.3 × 106 s⁻¹.

Abstract: Purpose : Data stability is a critical factor in ToF-SIMS single-cell analysis. However, various factors, such as sample processing, instrument condition, and data acquisition, can introduce uncertainties into ToF-SIMS data. Correcting this data is vital, yet current methods mainly focus on total ion current normalization or using consistent substrates. No specific correction method exists for ToF-SIMS single-cell metabolomics. Methods: This study utilizes the Norm-SVR, commonly used methods for correcting large-scale metabolomics data, for the correction of ToF-SIMS single-cell metabolomic analysis and assesses its performance in comparison to traditional total ion current normalization. Results and Conclusion: The results suggest that Norm-SVR effectively diminishes batch effects and reduces variability, thereby underscoring the method's efficacy and practicality. This approach is expected to improve data quality assurance in extensive ToF-SIMS analytical datasets.

Abstract: Extreme environments such as low pressure, high temperature, and intense radiation pose severe challenges for humidity sensors, causing conventional hygroscopic materials to exhibit sluggish responses, drift, and instability. In response, recent research has adopted multi-level strategies involving material modification, structural engineering, and packaging optimization to enhance the adaptability of humidity-sensitive materials in extreme environments. This review examines humidity sensing from an environmental perspective, integrating sensing mechanisms, material classifications, and application scenarios. The performance, advantages, and limitations of six major categories of humidity-sensitive materials, including carbon-based, metal oxides, conductive and insulating polymers, two-dimensional (2D) materials, and composites, are systematically summarized under extreme conditions. Finally, emerging development trends are discussed, highlighting a shift from material-driven to system-driven approaches. Future progress will rely on multidisciplinary integration, including interface engineering, multiscale structural design, and intelligent algorithms, to achieve higher accuracy, stability, and durability in extreme-environment humidity sensing.

Abstract: Silicon multilayer thin films consisting of alternating amorphous SiOx (a-SiOx) and nanocrystalline silicon (nc-Si) layers were fabricated on p-type silicon substrates using a sol-gel spin-coating method. Boron-doped silicon powders, prepared through pro-longed grinding, were mixed with a TEOS–ethanol sol-gel solution, and two nc-Si layers embedded in a-SiOx were sequentially deposited. The as-grown films were an-nealed at 100–400 °C and characterized using Raman spectroscopy, GXRD, FTIR, SEM, Resistivity and UV spectroscopy to analyze their structural, chemical, optical, and electronic properties. Annealing progressively enhanced crystallinity and increased the < 111> and < 110> grain sizes to ~11 nm and ~12 nm, respectively. Films annealed at higher temperatures showed a minimum mobility of ~37.5 cm²/V·s, maximum resis-tivity of ~7.35 Ω·cm, and a decreasing optical bandgap. Enhanced nanocrystal growth, reduced defects, and improved structural ordering intensified the 520 cm⁻¹ Raman peak. The multilayer architecture further strengthened these effects by offering addi-tional nucleation sites, controlled nanocrystal confinement, defect-relaxing interfaces, improved phonon transport, and enhanced Si diffusion, resulting in superior crystal-line quality.

Abstract:

Hydrogen, as an alternative energy carrier, presents significant prospects for the transition to more environmentally friendly energy solutions. However, its efficient and safe storage remains a challenge, as materials with high adsorbent capacity and long-term storage capability are required. This study focuses on the synthesis and characterization of a composite material consisting of carbon fiber and manganese dioxide (MnO₂/CFs), for the purpose of storing hydrogen. Carbon fiber was chosen as the basis for the composition of the composite material due to its large active surface area and its excellent mechanical, thermal, and electrochemical properties. The deposition of MnO₂ on the surface of carbon fibers took place through two different synthetic pathways: electrochemical deposition and chemical synthesis under different conditions. The electrochemical method allowed the development of oxide in more quantity, with optimized structural and chemical properties, while the chemical method had a more basic application but required more time to showcase same or less capacity performance. The elemental analysis of the electrochemically produced composites showcased an average of 40.60 wt% Mn presence, which is an indicator of the quantity of MnO₂ on the surface responsible for hydrogen storage, while the chemically produced showcased an average of 4.21 wt% Mn presence. Manganese oxide’s high specific capacity and reversible redox reaction participation make it suitable for hydrogen storage applications. The obtained results of the hydrogenated samples through physicochemical characterization indicated the formation of the MnOOH intermediate. These findings may be remarked that carbon fiber/MnO₂ composites are promising candidates for hydrogen storage technologies. Finally, the fabricated carbon fiber/MnO₂ composites were applied successfully as working electrodes for analysis of [Fe(CN)₆]^3-/4- redox system in aqueous KCl solutions.

Abstract: A comprehensive study of the thermodynamic conditions (temperature, composition) of the existence of the cubic phase within the limits of homogeneity region in the quasi-binary PbF2-EuF3 system was carried out. Solid solution samples were obtained by solid-phase synthesis and co-precipitation technique from aqueous nitrate solutions. Phase equilibria were investigated in two regions: the solvus line in the range of 0-10 mol% EuF3 and the region of existence of the ordered rhombohedral R-phase in the range of 35-45 mol% EuF3. The structure of phases in the PbF2-EuF3 system was examined at temperatures below the phase transition temperature in lead fluoride (365°C). The possibility of obtaining a single-phase preparation of a cubic phase of high purity in 0-37 mol% EuF3 composition range has been demonstrated. The region of existence of the ordered rhombohedral R-phase in the concentration range from 37-39 to 43-44 mol% EuF3 was defined using X-ray phase analysis, optical probing, and Raman scattering.

Abstract:

The article presents the method how prepare of a green composite material composed of cellulose and lignin using an ionic liquid as a solvent. In the process, cellulose and lignin are dissolved in the ionic liquid and subsequently regenerated into a composite film via coagulation in ethanol/water bath. The research focused on evaluating the mechanical properties of the resulting composite, which exhibited a high tensile strength exceeding 100 MPa, demonstrating its robustness and potential for various applications. Additionally, the biodegradation behavior of the composite in soil was investigated, showing that it gradually decomposes, making it environmentally friendly. Toxicity tests on soil bacteria indicated that the composite does not adversely affect microbial activity, supporting its suitability for ecological use. Furthermore, the gas permeability and water vapor transmission of the composite film was assessed, providing insight into its barrier properties. Overall, the study highlights the potential of cellulose-lignin composites produced via ionic liquids as sustainable and biodegradable materials with promising mechanical and environmental properties.

Abstract:

Transparent conductive materials (TCMs) are essential for optoelectrical devices ranging from smart windows and defogging films to soft sensors, display technologies and flexible electronics. Materials such as indium tin oxide (ITO) and silver nanowires (AgNWs) are commonly used and offer high optical transmittance and electrical conductivity but suffer from brittleness, oxidation susceptibility, and require high-cost materials, greatly limiting their use. Carbon nanotube (CNT) networks provide a promising alternative, featuring mechanical compliance, chemical robustness, and scalable processing. This study reports an aqueous ink formulation composed of ultra-long mix walled carbon nanotubes (UL-CNTs), compatible for flow coating process, yielding uniform transparent conductive films (TCFs) on polyethylene terephthalate (PET), glass, and polycarbonate (PC). The resulting films exhibit tunable transmittance (85-88% for single layers; ~57% for three layers at 550 nm) and sheet resistance of 7.5 kΩ/□ to 1.5 kΩ/□ accordingly. These TCFs maintain stable sheet resistance for over 5,000 bending cycles and show excellent mechanical durability with negligible effects on heating performance. Post-deposition treatments,including nitric acid vapor doping or flash photonic heating (FPH), further reduce sheet resistance by up to 80% (7.5 kΩ/□ to 1.2 kΩ/□). X-ray photoelectron spectroscopy (XPS) results in reduced surface oxygen content after FPH. The photonic-treated heaters attain ~100 °C within 20 seconds at 100 V. This scalable, water-based process provides a pathway toward low-cost, flexible and stretchable devices in a variety of fields including printed electronics, optoelectronics and thermal actuators.