Synthesis, Structural and Electrochemical Characterization of Carbon Fiber/MnO₂ Composites for Hydrogen Storage

Hydrogen, as an alternative energy carrier, presents significant prospects for the transition to more environmentally friendly energy solutions. However, its efficient and safe storage remains a challenge, as materials with high adsorbent capacity and long-term storage capability are required. This study focuses on the synthesis and characterization of a composite material consisting of carbon fiber and manganese dioxide (MnO₂/CFs), for the purpose of storing hydrogen. Carbon fiber was chosen as the basis for the composition of the composite material due to its large active surface area and its excellent mechanical, thermal, and electrochemical properties. The deposition of MnO₂ on the surface of carbon fibers took place through two different synthetic pathways: electrochemical deposition and chemical synthesis under different conditions. The electrochemical method allowed the development of oxide in more quantity, with optimized structural and chemical properties, while the chemical method had a more basic application but required more time to showcase same or less capacity performance. The elemental analysis of the electrochemically produced composites showcased an average of 40.60 wt% Mn presence, which is an indicator of the quantity of MnO₂ on the surface responsible for hydrogen storage, while the chemically produced showcased an average of 4.21 wt% Mn presence. Manganese oxide’s high specific capacity and reversible redox reaction participation make it suitable for hydrogen storage applications. The obtained results of the hydrogenated samples through physicochemical characterization indicated the formation of the MnOOH intermediate. These findings may be remarked that carbon fiber/MnO₂ composites are promising candidates for hydrogen storage technologies. Finally, the fabricated carbon fiber/MnO₂ composites were applied successfully as working electrodes for analysis of [Fe(CN)₆]^3-/4- redox system in aqueous KCl solutions.